catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2 N:N′] perchlorate hemihydrate]
نویسندگان
چکیده
In the title coordination polymer, {[Ag(C(12)H(20)N(2)O(2))]ClO(4)·0.5H(2)O}(n), the Ag(I) cation is coordinated by two N atoms from two 1,2-bis-(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N-Ag-N = 171.07 (8)°]. The L ligand bridges adjacent Ag(+) cations, forming a polymeric chain running along the c axis. The lattice water mol-ecule is situated on a twofold rotation axis, and links to the perchlorate anion via an O-H⋯O hydrogen bond. The long Ag⋯O separation of 3.200 (4) Å indicates a weak inter-action between the perchlorate anion and the Ag(I) cation. Weak C-H⋯O hydrogen bonding occurs between the chain and the lattice water mol-ecule and between the chain and perchlorate anions. Both five-membered rings of the L ligand display envelope conformations; in one five-membered ring, the flap C atom is disordered on opposite sides of the ring with occupancies of 0.65 and 0.35.
منابع مشابه
Tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2 N:N′]tetrakis(μ-methanolato-κ2 O:O)bis(μ-perchlorato-κ2 O:O′)tetracopper(II) bis(perchlorate)
The title tetra-nuclear Cu(II) complex, [Cu(4)(C(12)H(12)N(2)O(2))(4)(CH(3)O)(4)(ClO(4))(2)](ClO(4))(2), is located around an inversion center. Each Cu(II) atom is coordinated by two cis-O atoms from two bridging methano-late anions and two cis-N atoms from two bridging 1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in the basal plane, and is further coordinated by one O atom of the b...
متن کاملcatena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2 N:N′]
In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Each L ligand also lies across an inversion center and bridges two Cu(II) ions, forming a polymeric...
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In the title coordination polymer, [CdBr(2)(C(12)H(12)N(2)O(2))](n), the Cd(II) ion, situated on an inversion centre, is coordinated by four bridging Br atoms and two N atoms from two 1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted octa-hedral geometry. The L ligand, which also lies across an inversion centre, bridges two Cd(II) ions, forming layers parallel to (010).
متن کاملPoly[[μ2-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2 N:N′]di-μ2-chlorido-cadmium]
In the title coordination polymer, [CdCl(2)(C(12)H(12)N(2)O(2))](n), the Cd(II) ion, situated on an inversion center, is coordinated by four bridging Cl atoms and two N atoms from two 1,4-bis-(4,5-dihydro-1,3--oxazol-2-yl)benzene (L) ligands in a distorted octa-hedral geometry. Each L ligand also lies across an inversion center and bridges two Cd(II) ions, forming infinite two-dimensional recta...
متن کاملcatena-Poly[[diaquabis[2-(3-oxo-1,3-dihydro-2-benzofuran-1-yl)acetato-κO]cobalt(II)]-μ-1,2-bis(pyridin-4-yl)ethane-κ2 N:N′]
In the title complex, [Co(C(10)H(7)O(4))(2)(C(12)H(12)N(2))(H(2)O)(2)](n), the Co(II) ion is located on a crystallographic centre of symmetry and is six-coordinated by two N atoms from two 1,2-bis-(4-pyrid-yl)ethane ligands, two carboxylate O atoms from two 1,3-dihydro-3-oxo-1-isobenzofuran-acetate ligands and two terminal water ligands. The 1,2-bis(4-pyrid-yl)ethane ligands act as bidentate li...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012